Chemistry

Cannizaro reaction: Related question; DCC Reagent(dicyclohexylcarbodiimide) Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+   a)Ethyl acetoacetate(CH3COCH2COOCH2CH3) reactions with 1)NaoEt 2)CH3CH2Br 3)NaOH/H2o 4)H3o+ b)2Ethyl acetate (2CH3COOEt) reaction with NaOEt/H3o+ c)Diethyl malonate (CH2 (COOEt)2 )reaction with 1)NaoEt 2) CH3CH2Br 3)H3O+ Toluene(Ph CH3) reaxts with1) NBS/hv,2)Pph3,Buli and 3)Acetone

Robinson annelation reaction conjugated adition reaction or Michael addition reaction followed by intermolecular aldol and dehydration process is called Robinson annelation reaction in Robinson annelation reaction since the cyclisation  involve hence always thermodynamically controlled enolate ion formed initially and major product is dehydration product. since the Robinson annelation reaction is always thermodynamically controlled so we cannot obtain kinetically controlled less substituted product related question; oxidation of alcohol ,Types of alcohol,strong oxidizing agentsweak oxidizing agents Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+ Activity coefficient calculation example ,Debye-Huckel equation,ionic strength determination

Introduction the functional group of alcohol is -OH. the first member of alcohol family is methanol. alcohols are polar in nature they are they are generally in liquid form due to strong intermolecular hydrogen bonding. Types of alcohol alcohols are divided into 3 categories  a)1 degree alcohol or primary alcohol  b)2 degree alcohol or secondary alcohol c)3 degree alcohol or tertiary alcohol. primary alcohols are -ch2oh  secondary alcohols are -choh  tertiary alcohols are -coh depending upon the oxidizing agents different alcohols are oxidised to different compound strong oxidizing agents are KMnO4 ,K2 cr2o7/ concentrated H2SO4 , na2cr2o7/ concentrated H2SO4. when primary alcohols are oxidized by strong oxidizing agents than acid formed  for example methanols become methanoic acid or formic acid  ethanol oxidized to ethanoic acid or acetic acid  propanol oxidised to  propanoic acid  butanol oxidized to butanoic acid  pentanol oxidised t...

Definition muffet oxidation is the oxidation of alcohol by DCC reagent in dmso solvent. DCC reagent is a mild oxidizing agent which convert primary alcohol to aldehyde and secondary alcohol to ketone. Related questions 1. oxidation of of alcohol 2. oxidizing agent in organic compound 3. identification of degree of alcohol 4. Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+ 5. Tributyltin tin hydride(Bu3SnH) preparation,reduction of alkyl halide ,nitro group,AIBN structure

Introduction: methane and Ethane both are hydrocarbon and they are belongs to alkene family the formula of methae is ch4 and the formula of Ethane is c2h6. how to convert methane to ethane there are two process by which we can convert methane to ethane   process 1  firstly we can we convert  methane to methyl chloride by treating methane with chlorine in presence of sunlight (halogenation reaction) after that methyl chloride convert to Ethane via wurtz reaction in which methyl chloride treated with sodium in presence of dry  ether solvent . process 2  In grignard reaction firstly we convert methyl chloride to methyl magnesium chloride by reacting methyl chloride with magnesium in dry ether solvent in the second step of grignard reaction methyl magnesium chloride react with methyl chloride and it produced  Ethane . Methane to ethane Ethan to methane conversion the carbon number in ethane is 2 and the carbon number in methane is 1 so we need to decrease the...

Gilmann reagent  gilmann reagent is a organocopper agent  it is a source of  nucleophile  it works at minus 78 degree temperature 

 DDQ reagent  full form of DDQ reagent is dichloro dicyano quinone

 Tributyltin hydride(Bu3SnH)  Bu3snH is widely used for the reduction of carbon halogen Bond to carbon hydrogen bond  preparation of tributyl tin hydride  application of tributyl tin hydride  1.reduction of alkyl halide to alkane 2. reduction of nitro group to to alkane  structure of a AIBN  full form of AIBN AIBN is azabis iso butter nitrile Mechanism of reaction

  Definition of electrophile : electrophiles are electron deficient species which are attacked by electron rich species.

The full form of DCC is dicyclohexylcarbodiimide Structure of DCC  preparation of DCC  Application of DCC  DCC is used for 1. esterification  2.peroxide formation   3.anhydride formation  4.alpha beta unsaturated carbonyl compound from beta hydroxy carbonyl . Moffat oxidation Related questions 1. Moffut oxidation #oxidation of alcohol by DCC #Dcc reagent 2. LDA regent,LDA reaction with carbonyl compound,LDA reaction with ester,LDA reaction with alkyl halideLDA/PhSeBr/H2O2 reagent,LDA/ MeI with carbonyl compound LDA/PhCho reagent,

Reaction 1:Ethyl acetoacetate reactions with 1)NaOEt 2)CH3CH2Br 3)NaOH/H2O 4)H3O+

This is organic reaction with different reagent in sequence.  Step 1: Toluene (C6H6 CH3/PhCH3)reacts with NBS in presence of light (hv)

Conversation of cyclopentane to cyclopentanone