oxidation of alcohol ,Types of alcohol,strong oxidizing agentsweak oxidizing agents
Introduction
the functional group of alcohol is -OH.
the first member of alcohol family is methanol. alcohols are polar in nature they are they are generally in liquid form due to strong intermolecular hydrogen bonding.
Types of alcohol
alcohols are divided into 3 categories
a)1 degree alcohol or primary alcohol
b)2 degree alcohol or secondary alcohol c)3 degree alcohol or tertiary alcohol.
primary alcohols are -ch2oh
secondary alcohols are -choh
tertiary alcohols are -coh
depending upon the oxidizing agents different alcohols are oxidised to different compound
strong oxidizing agents are KMnO4 ,K2 cr2o7/ concentrated H2SO4 ,
na2cr2o7/ concentrated H2SO4.
when primary alcohols are oxidized by strong oxidizing agents than acid formed
for example methanols become methanoic acid or formic acid
ethanol oxidized to ethanoic acid or acetic acid
propanol oxidised to propanoic acid
butanol oxidized to butanoic acid
pentanol oxidised to pentanoic acid
when two degree alcohols are oxidized by strong oxidizing agents they form keto compound
for example propan-2-ol oxidized to propan 2 one
but-2-ol goes to but-2-one
pent 2-ol goes to pent - 2 one
tertiary alcohol are are not oxidized by strong oxidizing agent
weak oxidizing agents are PCC or piditonium chlorochromate,
PDC , swern oxidation, dmp etc.when primary alcohol are oxidized by week oxidizing agents they becomes aldehyde
for example methanol becomes methanal or formaldehyde
ethanol becomes ethanal or acetal dehyde
propanol becomes propanal
butanol becomes butanal
pentanal becomes pentanal.
when secondary alcohols are oxidised by week oxidizing agents they formed keto compounds
for example
propan-2-ol oxidized to propan 2 one
but-2-ol goes to but-2-one
pent 2-ol goes to pent - 2 one
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