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Showing posts from September, 2020

Grignard reagent,schlenk equilibrium of grignard reagent,preparation of aldehyde,ketone,alcohol,acid,amine by grignard regent,

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Grignard reagent  Grignard reagent is a organomagnesium compound metal directly connected to carbon it is an example of umplong reagent

Gilmann reagent(R2culi)

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Gilmann reagent  gilmann reagent is a organocopper agent  it is a source of  nucleophile  it works at minus 78 degree temperature 

DDQ reagent(dichloro dicyano quinone)

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 DDQ reagent  full form of DDQ reagent is dichloro dicyano quinone

Tributyltin tin hydride(Bu3SnH) preparation,reduction of alkyl halide ,nitro group,AIBN structure

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 Tributyltin hydride(Bu3SnH)  Bu3snH is widely used for the reduction of carbon halogen Bond to carbon hydrogen bond  preparation of tributyl tin hydride  application of tributyl tin hydride  1.reduction of alkyl halide to alkane 2. reduction of nitro group to to alkane  structure of a AIBN  full form of AIBN AIBN is azabis iso butter nitrile Mechanism of reaction

Electrophiles and Nucleophilic in reagent chemistry

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  Definition of electrophile : electrophiles are electron deficient species which are attacked by electron rich species.

DCC Reagent(dicyclohexylcarbodiimide)

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The full form of DCC is dicyclohexylcarbodiimide Structure of DCC  preparation of DCC  Application of DCC  DCC is used for 1. esterification  2.peroxide formation   3.anhydride formation  4.alpha beta unsaturated carbonyl compound from beta hydroxy carbonyl . Moffat oxidation Related questions 1. Moffut oxidation #oxidation of alcohol by DCC #Dcc reagent 2. LDA regent,LDA reaction with carbonyl compound,LDA reaction with ester,LDA reaction with alkyl halideLDA/PhSeBr/H2O2 reagent,LDA/ MeI with carbonyl compound LDA/PhCho reagent,